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@PhDThesis{Rodrigues:2023:COFlRe,
               author = "Rodrigues, Celina C{\^a}ndida Ferreira",
                title = "The CO2 fluxes and their relationship to environmental conditions 
                         on the Southwest Atlantic Ocean and its southern ocean sector",
               school = "Instituto Nacional de Pesquisas Espaciais (INPE)",
                 year = "2023",
              address = "S{\~a}o Jos{\'e} dos Campos",
                month = "2022-12-19",
             keywords = "CO2 flux, bulk methodology, eddy covariance, Southwest Atlantic 
                         Ocean, Southern Ocean, fluxo de CO2, metodologia bulk, 
                         covari{\^a}ncia de vort{\'{\i}}ces turbulentos, Oceano 
                         Atl{\^a}ntico Sudoeste, Oceano Austral.",
             abstract = "The oceans play an important role in mitigating climate change by 
                         acting as large carbon sinks, especially at middle and high 
                         latitude regions. The main objective of this work is to 
                         investigate the behavior of turbulent CO2 fluxes at medium- and 
                         high-latitude under different atmospheric and oceanic conditions, 
                         during the trajectories of research ships to the Southwest 
                         Atlantic Ocean and its portion in the Southern Ocean. The CO2 flux 
                         was calculated using the eddy covariance and bulk methodology. 
                         During the experiment the Brazil Current sink more CO2 than 
                         Malvinas Current, owing to its proximity to the chlorophyll-rich 
                         and less saline waters of the La Plata River, and intense wind 
                         speeds increased the CO2 flux between the ocean and atmosphere. 
                         The Brazil Malvinas Confluence also behaved as a CO2 sink, and the 
                         modulation of CO2 fluxes was due to the intense horizontal 
                         gradient of SST together with the moderate surface wind and 
                         turbulence. The MC sequestered less carbon than other regions 
                         because of the presence of a high-pressure system near the region, 
                         low atmospheric turbulence, and light surface winds that inhibited 
                         mass exchange between the ocean and atmosphere. The Bransfield 
                         Strait uptake 38.59% more CO2 than the Drake Passage due to the 
                         cold and fresh waters, allied to the influence of glacial 
                         meltwater dilution. The Drake Passage, on average, behaved as a 
                         CO2 sink, mainly due to physical characteristics. To minimize the 
                         uncertainty in bulk methodology for CO2 flux, we found the best 
                         fit for the gas transfer coefficient was K = 0.2325*u2 0.4361*u+ 
                         1.764 with R2 of 0.97, and it showed an adequate representation of 
                         ocean-atmosphere fluxes for Southwest Atlantic Ocean. The bulk 
                         methodology the purpose gas transfer coefficient had good 
                         agreement with the in situ data (eddy covariance) for the ACEx and 
                         and Antarctic Operations 32, 33, 34, and 37 (2012 to 2018). The 
                         Southwest Atlantic Ocean had been increasing the assimilation of 
                         carbon along the years analyzed (2003 to 2020), mainly due to the 
                         increase of CO2 concentration in the atmosphere. This research 
                         contributes to a better understanding of the Southwest Atlantic 
                         Ocean and Southern Oceans role in the global carbon balance. 
                         RESUMO: Os oceanos desempenham um papel importante na 
                         mitiga{\c{c}}{\~a}o das mudan{\c{c}}as clim{\'a}ticas, atuando 
                         como grandes sumidouros de carbono, especialmente nas regi{\~o}es 
                         de latitudes m{\'e}dias e altas. O principal objetivo deste 
                         trabalho {\'e} investigar o comportamento dos fluxos turbulentos 
                         de CO2 em latitudes m{\'e}dias e altas sob diferentes 
                         condi{\c{c}}{\~o}es atmosf{\'e}ricas e oce{\^a}nicas, durante 
                         as trajet{\'o}rias de navios de pesquisa para o Oceano 
                         Atl{\^a}ntico Sudoeste e sua por{\c{c}}{\~a}o no Oceano 
                         Austral. O fluxo de CO2 foi calculado usando a covari{\^a}ncia de 
                         v{\'o}rtices turbulentos e a metodologia bulk. Durante o 
                         experimento, a Corrente do Brasil sequestrou mais CO2 do que a 
                         Corrente das Malvinas, devido {\`a} sua proximidade com as 
                         {\'a}guas ricas em clorofila e menos salinas do Rio da Prata, e 
                         ventos intensos aumentaram o fluxo de CO2 entre o oceano e a 
                         atmosfera. A Conflu{\^e}ncia Brasil Malvinas tamb{\'e}m se 
                         comportou como um sumidouro de CO2, devido ao intenso gradiente 
                         horizontal de temperatura da superf{\'{\i}}cie do mar, junto com 
                         ventos moderados e turbul{\^e}ncia. A corrente das Malvinas 
                         sequestrou menos carbono do que outras regi{\~o}es devido {\`a} 
                         presen{\c{c}}a de um sistema de alta press{\~a}o pr{\'o}ximo 
                         {\`a} regi{\~a}o, baixa turbul{\^e}ncia e ventos fracos na 
                         superf{\'{\i}}cie que inibiram a troca de massa entre o oceano e 
                         a atmosfera. O Estreito de Bransfield absorveu 38,59% mais CO2 do 
                         que a Passagem de Drake devido {\`a}s {\'a}guas frias e menos 
                         salinas, aliadas {\`a} influ{\^e}ncia do degelo glacial. A 
                         Passagem de Drake, em m{\'e}dia, comportouse como um sumidouro de 
                         CO2, principalmente devido {\`a}s caracter{\'{\i}}sticas 
                         f{\'{\i}}sicas. Para minimizar as incertezas na metodologia bulk 
                         para o c{\'a}lculo do fluxo de CO2, encontramos o melhor ajuste 
                         para o coeficiente de transfer{\^e}ncia de g{\'a}s foi K = 
                         0,2325*u2 0,4361*u+ 1,764 com R2 de 0,97, esse mostrou uma 
                         representa{\c{c}}{\~a}o adequada dos fluxos para o 
                         Atl{\^a}ntico Sudoeste. A metodologia de bulk, aplicando o 
                         coeficiente de transfer{\^e}ncia de g{\'a}s proposto, teve boa 
                         concord{\^a}ncia com os dados in situ (covari{\^a}ncia de 
                         v{\'o}rtices turbulentos) para o ACEx e para as 
                         Opera{\c{c}}{\~o}es Ant{\'a}rticas 32, 33, 34 e 37 (2012 a 
                         2018). O Oceano Atl{\^a}ntico Sudoeste vem aumentando a 
                         assimila{\c{c}}{\~a}o de carbono ao longo dos anos analisados 
                         (2003 a 2020), principalmente devido ao aumento da 
                         concentra{\c{c}}{\~a}o de CO2 na atmosfera. Esta pesquisa 
                         contribui para uma melhor compreens{\~a}o do papel do Oceano 
                         Atl{\^a}ntico Sudoeste e do Oceano Austral no balan{\c{c}}o 
                         global de carbono.",
            committee = "Valeriano, M{\'a}rcio de Morisson (presidente) and Pezzi, Luciano 
                         Ponzi (orientador) and Santini, Marcelo Freitas (orientador) and 
                         Cunha, Leticia Cotrim da and Lef{\`e}vre, Nathalie",
         englishtitle = "Os fluxos de CO2 e sua rela{\c{c}}{\~a}o com as 
                         condi{\c{c}}{\~o}es ambientais no Oceano Atl{\^a}ntico Sudoeste 
                         e seu setor no Oceano Austral",
             language = "en",
                pages = "75",
                  ibi = "8JMKD3MGP3W34T/48GESAL",
                  url = "http://urlib.net/ibi/8JMKD3MGP3W34T/48GESAL",
           targetfile = "publicacao.pdf",
        urlaccessdate = "20 maio 2024"
}


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