@Article{DinizFerrCoraTrav:2002:BoDoDi,
               author = "Diniz, Alessandra Ven{\^a}ncio and Ferreira, Neidenei Gomes and 
                         Corat, Evaldo Jos{\'e} and Trava-Airoldi, Vladimir Jesus",
          affiliation = "ITA, S{\~a}o Jos{\'e} dos Campos - SP",
                title = "Boron doped diamond thin films on large area Ti6AL4V substrates 
                         for electrochemical application",
              journal = "Materials Research",
                 year = "2002",
               volume = "6",
               number = "1",
                pages = "57--61",
                month = "jan./fev.",
             keywords = "boron doped-diamond, Ti6AL4V, electrochemistry.",
             abstract = "Boron doped diamond thin films were grown on titanium alloy 
                         substrates (Ti6Al4V) with 36 × 35 × 1.3 mm at 873-933 K at 6.5 × 
                         103 Pa during 8 h by hot filament CVD assisted technique. The 
                         boron source was obtained from a H2 line forced to pass through a 
                         bubbler containing B2O3 dissolved in methanol (BC = 6000 ppm). The 
                         films were grown on both sides of perforated and non-perforated 
                         substrates. Emphasis for diamond growing on perforated substrates 
                         have been done in order to increase the active surface area and 
                         hereafter to promote an easier electrolyte flow for wastewater 
                         treatment. The electrode performance was determined by cyclic 
                         voltammetry measurements in KCl, KNO3, Na2SO4, HCl, HNO3 and H2SO4 
                         solutions and the reversibility behavior of the Fe(CN)63-/4- at 
                         the Ti6AL4V/Diamond electrode were studied. Also, Scaning Electron 
                         Microcopy and Raman Scattering Spectroscopy were used for 
                         morphology and diamond quality evaluation, respectively.",
           copyholder = "SID/SCD",
            isbn/issn = "1516-1439",
                 issn = "1516-1439",
             language = "en",
           targetfile = "v6n1a11.pdf",
        urlaccessdate = "16 jun. 2024"
}