@Article{FerreiraMendTravRoso:2003:ElInLi,
               author = "Ferreira, Neidenei Gomes and Mendonca, L. L. and Trava-Airoldi, 
                         Vladimir Jesus and Rosolen, J. M.",
          affiliation = "{Instituto Nacional de Pesquisas Espaciais (INPE)} and 
                         Departamento de Qu{\'{\i}}mica, FFCLRP, Universidade de S{\~a}o 
                         Paulo and {Instituto Nacional de Pesquisas Espaciais (INPE)} and 
                         Departamento de Qu{\'{\i}}mica, FFCLRP, Universidade de S{\~a}o 
                         Paulo",
                title = "Electrochemical intercalation of lithium into boron-doped CVD 
                         diamond electrodes grown on carbon fiber cloths",
              journal = "Diamond and Related Materials",
                 year = "2003",
               volume = "12",
               number = "3-7",
                pages = "596--600",
                month = "Mar.-July",
             keywords = "lithium intercalation, electrochemical, doped-diamond, 
                         optical-emission, film electrodes, li.",
             abstract = "Boron-doped diamond electrodes grown on a cloth of graphite fibers 
                         have demonstrated as an innovative material electrode for lithium 
                         intercalation by electrochemical method. It was studied lithium 
                         electrochemical intercalation for samples with different levels of 
                         boron doping. Diamond films were grown by hot-filament-assisted 
                         chemical vapor deposition technique. Boron was obtained from a 
                         source of B2O3 dissolved in methanol. The electrochemical 
                         characterization was carried out by voltammetry cyclic and 
                         charge/discharge curves. The electrolyte used was 1 mol l(-1) of 
                         LiPF6 in mixture of ethylene carbonate, dimethyl carbonate and 
                         diethyl carbonate (1:1:1 wt.). The reference and work electrode 
                         were metallic lithium and the cell was assembled a dry-box. The 
                         results show that the insertion of lithium LixBzC1- z)(6) is 
                         reversible and presents specific capacity, which depend on 
                         B-concentration. For limits of cut-off potential of 3.0 e 0.01 V 
                         vs. lithium we found a reversible specific capacity of 88 mAh 
                         g(-1) (x similar to 0.23) for sample with similar to 10(18) B 
                         cm(-3) and 43 mAh g(-1) (x similar to 0.11) for sample with 10(21) 
                         B cm(-3). The voltage vs. capacity presents a hysteresis that 
                         increases with decreasing of boron concentration.",
           copyholder = "SID/SCD",
                  doi = "10.1016/S0925-9635(02)00273-X",
                  url = "http://dx.doi.org/10.1016/S0925-9635(02)00273-X",
            isbn/issn = "0925-9635",
                 issn = "0925-9635",
             language = "en",
           targetfile = "1-s2.0-S092596350200273X-main.pdf",
                  url = "http://dx.doi.org/10.1016/S0925-9635(02)00273-X",
        urlaccessdate = "29 jun. 2024"
}