@Article{AnjosBRECMAP:2022:InBlPr,
author = "Anjos, Erick Gabriel Ribeiro dos and Braga, Nat{\'a}lia Ferreira
and Ribeiro, Bruno and Escanio, Camila Alves and Cardoso, Andreza
de Moura and Marini, Juliano and Antonelli, Eduardo and Passador,
F{\'a}bo Roberto",
affiliation = "{Universidade Federal de S{\~a}o Paulo (UNIFESP)} and
{Universidade Federal de S{\~a}o Paulo (UNIFESP)} and
{Universidade Federal de S{\~a}o Paulo (UNIFESP)} and {Instituto
Nacional de Pesquisas Espaciais (INPE)} and {Instituto de
Aeron{\'a}utica e Espa{\c{c}}o (IAE)} and {Universidade Federal
de S{\~a}o Carlos (UFSCar)} and {Universidade Federal de S{\~a}o
Paulo (UNIFESP)} and {Universidade Federal de S{\~a}o Paulo
(UNIFESP)}",
title = "Influence of blending protocol on the mechanical, rheological, and
electromagnetic properties of PC/ABS/ABS-g-MAH blend-based MWCNT
nanocomposites",
journal = "Journal of Applied Polymer Science",
year = "2022",
volume = "139",
number = "15",
pages = "e51946",
month = "Apr.",
abstract = "Polycarbonate (PC)/acrylonitrile-butadiene-styrene copolymer (ABS)
blend-based multi-wall carbon nanotubes (MWCNT) nanocomposites is
an attractive alternative for the manufacture of electronics
housing as it can have the mechanical and electromagnetic
properties required for this application. The preferred location
of MWCNT in PC/ABS blend is an important parameter to obtain
better mechanical and electromagnetic properties. In this way,
three different blending protocols (BP) were used to obtain
PC/ABS/maleic anhydride-grafted ABS (ABS-g-MAH) (85/10/5)
blend-based MWCNT nanocomposites with the addition of 0.5 and 1
wt% of MWCNT in a twin-screw extruder. Specimens were evaluated by
thermal (thermogravimetric analysisTGA and differential scanning
calorimetryDSC), mechanical (Izod impact strength and tensile
tests), dynamic mechanical analysis (DMA), electrical, and
rheological properties, which were correlated with the
nanocomposites morphology evaluated by high-resolution scanning
electron microscopy. The BP associated with the addition of a
compatibilizer agent influenced the MWCNT distribution and
location in the polymeric matrix. The one-step extrusion process
results in MWCNT mostly at the interface of the PC/ABS blend and
agglomerates, leading to lower mechanical and thermal properties.
The BP in which a PC/MWCNT masterbatch was first prepared and then
diluted in ABS and ABS-g-MAH achieves the higher mechanical
properties, increasing Young's modulus and the ultimate tensile
strength. The third BP in which MWCNT was added in a second step
in the blend already processed resulted in a homogeneous
dispersion of MWCNT on both phases and a lower electrical
resistivity.",
doi = "10.1002/app.51946",
url = "http://dx.doi.org/10.1002/app.51946",
issn = "0021-8995 and 1097-4628",
language = "en",
targetfile = "J of Applied Polymer Sci - 2021 - Anjos - Influence of blending
protocol on the mechanical rheological and (1).pdf",
urlaccessdate = "25 jun. 2024"
}