@Article{VernasquiSFKBFFL:2022:HiPoSe,
               author = "Vernasqui, La{\'{\i}}s Gimenes and Santos, Alexsandro J. dos and 
                         Fortunato, Guilherme V. and Kronka, Matheus S. and 
                         Barazorda-Ccahuana, Haruna L. and Fajardo, Ana S. and Ferreira, 
                         Neiden{\^e}i Gomes and Lanza, Marcos R. V.",
          affiliation = "{Instituto Nacional de Pesquisas Espaciais (INPE)} and 
                         {Universidade de S{\~a}o Paulo (USP)} and {Universidade de 
                         S{\~a}o Paulo (USP)} and {Universidade de S{\~a}o Paulo (USP)} 
                         and {Universidad Cat{\'o}lica de Santa Mar{\'{\i}}a} and 
                         {Arizona State University} and {Instituto Nacional de Pesquisas 
                         Espaciais (INPE)} and {Universidade de S{\~a}o Paulo (USP)}",
                title = "Highly porous seeding-free boron-doped ultrananocrystalline 
                         diamond used as high-performance anode for electrochemical removal 
                         of carbaryl from water",
              journal = "Chemosphere",
                 year = "2022",
               volume = "305",
                pages = "e135497",
                month = "Oct.",
             keywords = "Advanced oxidation processes, Boron-doped diamond synthesis, 
                         Electrochemical technologies, Recalcitrant pollutants, Water 
                         treatment.",
             abstract = "Boron-doped diamond (BDD) electrodes are regarded as the most 
                         promising catalytic materials that are highly efficient and 
                         suitable for application in advanced electrochemical oxidation 
                         processes targeted at the removal of recalcitrant contaminants in 
                         different water matrices. Improving the synthesis of these 
                         electrodes through the enhancement of their morphology, structure 
                         and stability has become the goal of the material scientists. The 
                         present work reports the use of an ultranano-diamond electrode 
                         with a highly porous structure (B-UNCDWS/TDNT/Ti) for the 
                         treatment of water containing carbaryl. The application of the 
                         proposed electrode at current density of 75 mA cm\−2 led to 
                         the complete removal of the pollutant (carbaryl) from the 
                         synthetic medium in 30 min of electrolysis with an electric energy 
                         per order of 4.01 kWh m\−3 order\−1. The results 
                         obtained from the time-course analysis of the carboxylic acids and 
                         nitrogen-based ions present in the solution showed that the 
                         concentrations of nitrogen-based ions were within the established 
                         maximum levels for human consumption. Under optimal operating 
                         conditions, the proposed electrode was successfully employed for 
                         the complete removal of carbaryl in real water. Thus, the findings 
                         of this study show that the unique, easy-to-prepare BDD-based 
                         electrode proposed in this study is a highly efficient tool which 
                         has excellent application potential for the removal of 
                         recalcitrant pollutants in water.",
                  doi = "10.1016/j.chemosphere.2022.135497",
                  url = "http://dx.doi.org/10.1016/j.chemosphere.2022.135497",
                 issn = "0045-6535",
             language = "en",
           targetfile = "1-s2.0-S0045653522019907-main.pdf",
        urlaccessdate = "25 jun. 2024"
}