@Article{RamlowSilMarBalMac:2024:CoHeSi,
author = "Ramlow, Heloisa and Silva, Liangrid Lutiani and Marangoni, Cintia
and Baldan, Maur{\'{\i}}cio Ribeiro and Machado, Ricardo Antonio
Francisco",
affiliation = "{Universidade Federal de Santa Catarina (UFSC)} and {Instituto
Nacional de Pesquisas Espaciais (INPE)} and {Universidade Federal
de Santa Catarina (UFSC)} and {Instituto Nacional de Pesquisas
Espaciais (INPE)} and {Universidade Federal de Santa Catarina
(UFSC)}",
title = "Corrosion and heat-resistant SiCN/C as lightweight fibers for
microwave absorption and electromagnetic field shielding in
Ku-band",
journal = "Diamond and Related Materials",
year = "2024",
volume = "144",
pages = "e110985",
month = "Apr.",
keywords = "Electrical permittivity, Electrospinning, Polymer-derived ceramic,
Rectangular waveguide aperture, Silicon carbonitride.",
abstract = "SiCN fibers are usually combined with metals to increase the
magnetic loss in electromagnetic field (EMF) shielding, but this
results in high weight density, easy corrosion, difficult
treatment, and high cost of the material. This study proposes the
manufacturing of corrosion and heat-resistant ceramic lightweight
fibers containing in-situ synthesized carbon nanostructures
(SiCN/C) with excellent EMF shielding in Ku-band (12.418 GHz). The
samples showed differential trends of EMF shielding effectiveness
in terms of reflectance, transmittance, and absorption behavior.
Compared to SiCN fibers, the EMF absorption was two times greater
when carbon was added to the SiCN matrix. A minimum reflection
coefficient (S11) of \−12 dB was observed for SiCN/C
fibers, meaning a high shielding efficiency with >90 % of the EMF
energy shielded. On the other hand, SiCN fibers showed a minimum
S11 of \−7 dB, resulting in a protection of 80 % against
EMF energy. Computational simulations clarified the better
features of SiCN/C in electromagnetic shielding compared to SiCN,
which was ascribed to enhanced conduction loss derived from
conductive free carbon, and dipole and interfacial polarization
loss generated by defects. The fibers were resistant to acidic and
basic environments and oxidation of up to 600 °C. Moreover, the
addition of carbon precursor represented a weight decrease of 17 %
for SiCN/C compared to SiCN fibers. This research will afford an
alternative solution for the manufacturing of SiCN/C fibers with
EMF absorption properties that can be used as lightweight
materials in harsh environments.",
doi = "10.1016/j.diamond.2024.110985",
url = "http://dx.doi.org/10.1016/j.diamond.2024.110985",
issn = "0925-9635",
language = "en",
targetfile = "1-s2.0-S0925963524001985-main.pdf",
urlaccessdate = "03 maio 2024"
}