| 1. Identity statement | |
| Reference Type | Journal Article |
| Site | mtc-m16b.sid.inpe.br |
| Holder Code | isadg {BR SPINPE} ibi 8JMKD3MGPCW/3DT298S |
| Identifier | 7nKX3pFwXQZ35cLJ/EkREr |
| Repository | lcp.inpe.br/ignes/2004/12.02.15.00 (restricted access) |
| Last Update | 2004:12.03.02.00.00 (UTC) administrator |
| Metadata Repository | lcp.inpe.br/ignes/2004/12.02.15.00.05 |
| Metadata Last Update | 2018:06.05.03.51.54 (UTC) administrator |
| Secondary Key | INPE--PRE/ |
| ISSN | 0095-8972 |
| Citation Key | MassabniCorMelZacRec:2004:SySpCh |
| Title | Synthesis and spectroscopic characterization of new metal (II) complexes with mehtionine sulfoxide  |
| Year | 2004 |
| Month | sept. |
| Access Date | 2024, Apr. 28 |
| Secondary Type | PRE PI |
| Number of Files | 1 |
| Size | 639 KiB |
| 2. Context | |
| Author | 1 Massabni, Antonio Carlos 2 Corbi, Pedro Paulo 3 Melnikov, Peter 4 Zacharias, Marisa Aparecida 5 Rechenberg, Hercílio R. |
| Resume Identifier | 1 2 3 4 8JMKD3MGP5W/3C9JHSF |
| Group | 1 LCP-INPE-MCT-BR |
| Affiliation | 1 UNESP, Instituto de Quimica 2 Universidade Federal do Mato Grosso do Sul, CCET 3 Instituto Nacional de Pesquisas Espaciaisl 4 USP, Instituto de Fisica |
| Journal | Journal of Coordination Chemistry |
| Volume | 57 |
| Number | 14 |
| Pages | 1225-1231 |
| History (UTC) | 2006-02-15 12:33:24 :: ignes -> administrator :: 2012-10-21 21:43:51 :: administrator -> ignes :: 2004 2013-02-20 14:54:11 :: ignes -> administrator :: 2004 2018-06-05 03:51:54 :: administrator -> marciana :: 2004 |
| 3. Content and structure | |
| Is the master or a copy? | is the master |
| Content Stage | completed |
| Transferable | 1 |
| Content Type | External Contribution |
| Keywords | acid iron |
| Abstract | Methionine sulfoxide complexes of iron(II) and copper(II) were synthesized and characterized by chemical and spectroscopic techniques. Elemental and atomic absorption analyses fit the compositions K-2[Fe(metSO)(2)]SO4 (.) H2O and [Cu(metSO)(2)](.) H2O. Electronic absorption spectra of the complexes are typical of octahedral eeometries. Infrared spectroscopy suggests coordination of the ligand to the metal through the carboxylate and sulfoxide groups. An EPR spectrum of the Cu(II) complex indicates tetragonal distortion of its octahedral symmetry. Fe-57 Mossbauer parameters are also consistent with octahedral stereochemistry for the iron(II) complex. The complexes are very soluble in water. |
| Area | COMB |
| Arrangement | Synthesis and spectroscopic... |
| doc Directory Content | access |
| source Directory Content | there are no files |
| agreement Directory Content | there are no files |
| 4. Conditions of access and use | |
| Language | en |
| Target File | synthesispec.pdf |
| User Group | administrator ignes |
| Visibility | shown |
| Archiving Policy | denypublisher denyfinaldraft12 |
| Read Permission | deny from all and allow from 150.163 |
| 5. Allied materials | |
| Next Higher Units | 8JMKD3MGPCW/3ET38CH |
| Dissemination | WEBSCI |
| Host Collection | lcp.inpe.br/ignes/2004/02.12.18.39 cptec.inpe.br/walmeida/2003/04.25.17.12 |
| 6. Notes | |
| Empty Fields | alternatejournal archivist callnumber copyholder copyright creatorhistory descriptionlevel documentstage doi e-mailaddress electronicmailaddress format isbn label lineage mark mirrorrepository nextedition notes orcid parameterlist parentrepositories previousedition previouslowerunit progress project readergroup rightsholder schedulinginformation secondarydate secondarymark session shorttitle sponsor subject tertiarymark tertiarytype typeofwork url versiontype |
| 7. Description control | |
| e-Mail (login) | marciana |
| update | |