| 1. Identity statement | |
| Reference Type | Journal Article |
| Site | mtc-m16.sid.inpe.br |
| Holder Code | isadg {BR SPINPE} ibi 8JMKD3MGPCW/3DT298S |
| Identifier | 6qtX3pFwXQZ3r59YDa/HFBD2 |
| Repository | sid.inpe.br/iris@1916/2005/10.06.14.33 (restricted access) |
| Last Update | 2005:10.18.10.03.00 (UTC) administrator |
| Metadata Repository | sid.inpe.br/iris@1916/2005/10.06.14.33.59 |
| Metadata Last Update | 2018:06.05.01.16.12 (UTC) administrator |
| Secondary Key | INPE--13089-PRE/8349 |
| ISSN | 0009-2614 |
| Citation Key | RamalhoVileBarrGarg:2005:ThRaCo |
| Title | Theoretical rate constants for the reaction BF2+NF=BF3+N of importance in boron nitride chemistry  |
| Project | Tecnologia de Plasma: Processos a Plasma |
| Year | 2005 |
| Month | Sept. |
| Access Date | 2024, May 02 |
| Secondary Type | PRE PI |
| Number of Files | 1 |
| Size | 224 KiB |
| 2. Context | |
| Author | 1 Ramalho, S. S 2 Vilela, A. F. A. 3 Barreto, Patricia Regina Pereira 4 Gargano, R. |
| Resume Identifier | 1 2 3 8JMKD3MGP5W/3C9JJ2S |
| Group | 1 2 3 LAP-INPE-MCT-BR |
| Affiliation | 1 2 Univ Brasilia, Inst Fis, Brasilia 3 Instituto Nacional de Pesquisas Espaciais, Laboratório Associado de Plasmas, (INPE. LAP) |
| Journal | Chemical Physics Letters |
| Volume | 413 |
| Number | 1-3 |
| Pages | 151-156 |
| History (UTC) | 2005-10-18 10:03:31 :: sergio -> administrator :: 2006-09-28 22:30:19 :: administrator -> sergio :: 2008-01-07 12:53:08 :: sergio -> marciana :: 2008-01-08 17:04:29 :: marciana -> administrator :: 2018-06-05 01:16:12 :: administrator -> marciana :: 2005 |
| 3. Content and structure | |
| Is the master or a copy? | is the master |
| Content Stage | completed |
| Transferable | 1 |
| Content Type | External Contribution |
| Keywords | PLASM Gas-phase reaction Thin films Abnitio Vibrational frequencies Matrix-isolation Abstraction Spectra Complex Atoms Boron PLASMA Reação de fase do gás Filmes Freqüências de vibração Isolamento matriz Abstração Atomos Boro |
| Abstract | A kinetic mechanism was developed for the growth of boron nitride films, including up to 35 species and 1012 gas-phase reactions. For 117 elementary reactions, rate constants are available from published experimental/theoretical data and a code was written to estimate the others using transition state theory. As an example of our approach, we report here results for one of these reactions, BF2 + NF = BF3 + N of presumable importance for the mechanism, using geometries and electronic energies (including their first and second derivatives), calculated ab initio along the minimum energy path. The reaction proceeds in two steps and rate constants were calculated for the temperature range 200-4000 K. |
| Area | FISPLASMA |
| Arrangement | urlib.net > BDMCI > Fonds > Produção anterior à 2021 > LABAP > Theoretical rate constants... |
| doc Directory Content | access |
| source Directory Content | there are no files |
| agreement Directory Content | there are no files |
| 4. Conditions of access and use | |
| Language | en |
| Target File | 87.pdf |
| User Group | administrator marciana sergio |
| Visibility | shown |
| Copy Holder | SID/SCD |
| Archiving Policy | denypublisher denyfinaldraft24 |
| Read Permission | deny from all and allow from 150.163 |
| 5. Allied materials | |
| Next Higher Units | 8JMKD3MGPCW/3ET2RFS |
| Dissemination | WEBSCI; PORTALCAPES; COMPENDEX. |
| Host Collection | sid.inpe.br/banon/2003/08.15.17.40 |
| 6. Notes | |
| Empty Fields | alternatejournal archivist callnumber copyright creatorhistory descriptionlevel documentstage doi e-mailaddress electronicmailaddress format isbn label lineage mark mirrorrepository nextedition notes orcid parameterlist parentrepositories previousedition previouslowerunit progress readergroup rightsholder schedulinginformation secondarydate secondarymark session shorttitle sponsor subject tertiarymark tertiarytype typeofwork url versiontype |
| 7. Description control | |
| e-Mail (login) | marciana |
| update | |